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The effect of a new additive zinc trifluoromethanesulfonate on the performance of perovskite solar cells

2025-06-10

Perovskite soLar cells have emerged as a rising star in the field of solar cells due to their high photoelectric conversion efficiency, low cost, and ease of preparation, becoming a focus of attention for researchers. However, perovskite solar cells still face many challenges in terms of stability and efficiency improvement. In recent years, research has found that the new additive zinc trifluoromethanesulfonate can effectively improve the performance of perovskite solar cells, bringing new hope for the development of this field.  

The performance of perovskite solar cells is influenced by various factors, among which the quality of perovskite thin films is crucial. Zinc trifluoromethanesulfonate, when added as an additive to the perovskite precursor solution, can play a crucial role in the growth process of perovskite films. On the one hand, it can regulate the growth kinetics of perovskite crystals, promote uniform crystal growth, reduce crystal defects and grain boundaries. Research has shown that the perovskite thin film prepared by adding zinc trifluoromethanesulfonate has a more regular crystal structure and significantly reduced defect density, which effectively reduces the recombination probability of charge carriers and improves the transport efficiency of charge carriers.  

On the other hand, zinc trifluoromethanesulfonate can also improve the interface contact between perovskite films and electrodes. Good interface contact helps to efficiently extract and transport charge carriers at the interface, reducing energy loss at the interface. By optimizing the interface properties, key performance parameters such as open circuit voltage, short-circuit current, and fill factor of perovskite solar cells have been significantly improved, thereby achieving higher photoelectric conversion efficiency. Meanwhile, the addition of zinc trifluoromethanesulfonate also enhances the stability of perovskite solar cells, enabling them to maintain good performance under different environmental conditions, providing strong support for the commercial application of perovskite solar cells.