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Exploration of green chemistry process based on silver trifluoromethanesulfonate catalytic system

2025-06-16

Against the backdrop of global advocacy for sustainable development, green chemical processes have become a research hotspot in the field of chemical engineering. Silver trifluoromethanesulfonate, with its excellent catalytic performance and environmentally friendly characteristics, has become an important component in building green chemical processes. The catalytic system based on silver trifluoromethanesulfonate provides new ideas and methods for achieving green and efficient chemical reactions.  

The greenness of the silver trifluoromethanesulfonate catalytic system is first reflected in its good recyclability. Traditional catalysts are often difficult to separate and recycle after the reaction is complete, which not only causes resource waste but also generates a Large amount of waste and pollutes the environment. Silver trifluoromethanesulfonate can be efficiently recovered through simple extraction, precipitation, and other methods, and its catalytic activity remains basically unchanged after multiple repeated uses. For example, in a certain esterification reaction, a supported silver trifluoromethanesulfonate catalyst was used. After 5 cycles of use, the conversion rate of the reaction remained above 90%, greatly reducing production costs and environmental burden.  

In addition, the catalytic system can be carried out under relatively mild reaction conditions. The lower reaction temperature and pressure not only reduce energy consumption, but also decrease the production of harmful substances during the reaction process. In some reactions involving toxic reagents, silver trifluoromethanesulfonate can catalyze the reaction in solvent-free or green solvent systems, avoiding the harm of organic solvents to the environment and human health. Meanwhile, the green chemistry process based on the silver trifluoromethanesulfonate catalytic system also has the advantage of high reaction selectivity, which can reduce the occurrence of side reactions, improve atomic utilization, and truly reduce the generation of pollutants from the source, in line with the core principles of green chemistry.